World

Usain Bolt, 29, Jamaica

Athletics, from Saturday 13

Bolt's hamstring injury at the start of July will only add to the

anticipation over the defence of his 100m and 200m titles in Rio. His rivalry

with controversial American Justin Gatlin will once again be the headline act of

the Games.

Dafne Schippers, 24, Netherlands

Athletics, from Friday 12

Three years ago Schippers was claiming a World Championship

bronze medal in heptathlon. Her stunning switch to sprinting - winning 200m gold

and 100m silver at the 2015 worlds - is set to lead to Olympic medals in Brazil.

Michael Phelps, 31, USA

Swimming, from Sunday 7

The most decorated Olympian of all time with 22 medals to his name, Phelps marked his return to the big stage by qualifying for Rio in three individual distances at the US Olympic trials at the age of 31. As well as the 100 and 200 butterfly and the 200 individual medley, he should also figure in three relay events.

Claressa Shields, 21, USA

Boxing, from Friday 12

The American shot to fame by claiming middleweight gold in London at the age of just 17. Invincible since, with two world titles to her name, Shields starts as the big favourite to become a double Olympic gold medallist.

Mehdi Khodabakhshi, 25, Iran

Taekwondo, Friday 19

Taekwondo stars do not come much more dominant than the Iranian, who heads to Rio as the reigning world and Asian Games champion in the men's 80kg division, and with a reputation which makes him a massive favourite for gold.

British

Jessica Ennis-Hill, 30

Athletics, Friday 12 and Saturday 13

It has been far from plain sailing for Ennis-Hill since her historic heptathlon triumph at Super Saturday in 2012. Since her return from time out to start a family, she has

shown glimpses of the form that swept her to gold in London, though she faces a stiff challenge for her crown, not least from compatriot Katarina Johnson-Thompson.

Adam Peaty, 21

Swimming, Saturday 6 and Sunday 7

The Englishman will head to Rio as the reigning world record-holder and world

champion in the 100m breaststroke, making him a huge favourite to

claim Great Britain's first men's Olympic swimming title since Adrian Moorhouse

in 1988.

Nicola Adams, 33

Boxing, from Friday 12

All-conquering Adams recently added the world title to her ever-growing

collection of honours at the fourth time of trying. The flyweight is set to

become the first Briton to retain an Olympic boxing gold medal since Harry

Mallin in 1924.

Lizzie Armitstead, 27

Cycling, Sunday 7

Pipped to road-race gold at London 2012 by Marianne Vos, Armitstead won the world title in Richmond, Virginia last year. Also the British and Commonwealth champion, she is the racer to beat in one of the first gold medal events of the Games.

Mo Farah, 33

Athletics, from Saturday 13

Farah faces a monumental task to repeat his double-winning feat of four years

ago. But he managed to claim both 5000m and 10,000m titles at last year’s IAAF World Championships, and will accept nothing less than a repeat performance in Rio.

Scottish

Laura Muir, 23

Athletics, from Friday 12

The 1500-metre runner has hit top form at exactly the right time, having broken Kelly Holmes’s British record at the Anniversary Games last weekend. Her growing tactical maturity combined with her fierce competitiveness gives her a fighting chance of a medal.

Andy Murray, 29

Tennis, from Saturday 6

Winning gold at London 2012 gave a massive boost to Murray, who went on to win the US Open that year and Wimbledon the following summer. Going into these Games as Wimbledon champion again, he stands an excellent chance of retaining his Olympic title.

Katie Archibald, 22

Cycling, from Thursday 11

With a world championship and six European titles under her belt, Archibald is part of a team pursuit squad that has an excellent chance of coming home with gold. She may lack the Olympic experience of team-mates such as Laura Trott, but after missing out on this year’s worlds through injury she is determined to make her talent count.

Lynsey Sharp, 26

Athletics, from Wednesday 17

The Commonwealth silver medallist faces tough opposition in an 800-metres field that includes the controversial South African Caster Semenya, but she proved in Glasgow that she can peak for the big race no matter how adverse the circumstances.

Katherine Grainger, 40

Rowing, from Saturday 6

Having won gold in the double sculls with Anna Watkins in London after three consecutive Olympic silvers, Grainger is now partnered by Vicky Thornley. The two only just made it into the British team at the last minute, but insist that their sights are still firmly on a medal.